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2,5-环己二烯-1,4-二亚胺

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2,5-环己二烯-1,4-二亚胺
别名 对苯醌二亚胺
PDI
识别
CAS号 4377-73-5  checkY
SMILES
 
  • N=C1C=CC(=N)C=C1
性质
化学式 C6H6N2
摩尔质量 106.13 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

2,5-环己二烯-1,4-二亚胺是一种有机化合物,化学式为C6H6N2。它可由对苯二胺经化学[1]或电化学[2]氧化得到:

H2NC6H4NH2 ⇌ HN=C6H4=NH + 2 H+ + 2 e

它可以和间苯二酚发生偶合反应,生成4-(4-氨基苯胺基)-1,3-苯二酚。[1]

参考文献

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  1. ^ 1.0 1.1 Aaron D. Bailey; Bryan P. Murphy; and Hairong Guan. Mechanistic Insights into Oxidative Oligomerization of p-Phenylenediamine and Resorcinol. J. Phys. Chem. A 2016, 120, 43, 8512–8520. doi:10.1021/acs.jpca.6b08571.
  2. ^ Sarawudh Nathabumroong, Chatwarin Poochai, Johannes Philipp Mensing, Chakrit Sriprachuabwong, Jaruwit Lohitkarn, Tanom Lomas, Rattikorn Yimnirun, and Adisorn Tuantranont. Violet Laser Treatment of Nitrogen-Doped Reduced Graphene Oxide Electrodes and KOH Electrolytes Containing p-Phenylenediamine for High-Performance Supercapacitors. ACS Appl. Nano Mater. 2023, 6, 1, 34–43. doi:10.1021/acsanm.2c03373.

延伸阅读

[编辑]
  • Nobuyuki Akai, Satoshi Kudoh, and Munetaka Nakata. UV Photolysis of 1,4-Diaminobenzene in a Low-Temperature Argon Matrix to 2,5-Cyclohexadiene-1,4-diimine via 4-Aminoanilino Radical. J. Phys. Chem. A 2003, 107, 34, 6725–6730. doi:10.1021/jp022694z.