四氯邻苯二酚
| 四氯邻苯二酚 | |
|---|---|
| |
| 别名 | 3,4,5,6-Tetrachloro-1,2-benzenediol, Tetrachloropyrocatechol |
| 识别 | |
| CAS号 | 1198-55-6 
|
| PubChem | 14537 |
| ChemSpider | 13880 |
| SMILES |
|
| Beilstein | 1876366 |
| Gmelin | 3937 |
| ChEBI | 26889 |
| KEGG | C18240 |
| 性质 | |
| 化学式 | C6H2Cl4O2 |
| 摩尔质量 | 247.89 g·mol−1 |
| 外观 | 白色固体 |
| 密度 | 1.848 g/cm3 (20 °C) |
| 熔点 | 194 °C（467 K） |
| 危险性 | |
GHS危险性符号  
| |
| GHS提示词 | Danger |
| H-术语 | H302, H318, H400 |
| P-术语 | P264, P264+265, P270, P273, P280, P301+317, P305+354+338, P317, P330, P391, P501 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
四氯邻苯二酚是一种有机氯化合物，化学式为C
6Cl
4(OH)
2，它是白色固体，由五氯酚的降解产生。[1]它可由四氯邻苯醌和1-甲基-1,4-环己二烯[2]或二硼酸[3]的还原反应制得。它是TRISPHAT的前驱体。它的共轭碱可作为过渡金属的配体。[4]
参考文献
[编辑]- ^ Oturan, Mehmet A.; Oturan, Nihal; Lahitte, Claude; Trevin, Stéphane. Production of hydroxyl radicals by electrochemically assisted Fenton's reagent. Journal of Electroanalytical Chemistry. 2001, 507 (1–2): 96–102. doi:10.1016/S0022-0728(01)00369-2.
- ^ Andrea Baschieri, Riccardo Amorati, Luca Valgimigli, Letizia Sambri. 1-Methyl-1,4-cyclohexadiene as a Traceless Reducing Agent for the Synthesis of Catechols and Hydroquinones. The Journal of Organic Chemistry. 2019-11-01, 84 (21): 13655–13664 [2023-02-16]. ISSN 0022-3263. doi:10.1021/acs.joc.9b01898. （原始内容存档于2023-02-16） （英语）.
- ^ Henian Peng, Tiejun Li, Duanshuai Tian, He Yang, Guangqing Xu, Wenjun Tang. Metal-free reduction of unsaturated carbonyls, quinones, and pyridinium salts with tetrahydroxydiboron/water. Organic & Biomolecular Chemistry. 2021, 19 (19): 4327–4337 [2023-02-16]. ISSN 1477-0520. doi:10.1039/D1OB00300C （英语）.
- ^ Ackermann, Jens; Meyer, Franc; Kaifer, Elisabeth; Pritzkow, Hans. Tuning the Activity of Catechol Oxidase Model Complexes by Geometric Changes of the Dicopper Core. Chemistry - A European Journal. 2002, 8 (1): 247–258. PMID 11822456. doi:10.1002/1521-3765(20020104)8:1<247::AID-CHEM247>3.0.CO;2-P.