鹼式乙酸鉻

鹼式乙酸鉻
識別
CAS號	160156-56-9
性質
化學式	C14H27Cr3O18
摩爾質量	639.34 g·mol−1
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

鹼式乙酸鉻是一種配位化合物，化學式為[Cr₃O(OAc)₆(H₂O)₃]OAc （OAc為CH₃CO₂⁻）。它可由氯化鉻六水合物和氫氧化鈉於水中反應，其沉澱再和無水乙酸反應製得；若和氘代乙酸反應，則得到[Cr₃O(O₂CD₃)₆(H₂O)₃](O₂CCD₃)。^[1]它在DMF中和苯甲酸煮沸後，再和高氯酸反應，可以得到[Cr₃O(OPh)₆(H₂O)₃]ClO₄·solv。^[2]它和矽鉬酸鉀在pH 2下反應，可以得到KH₂[Cr₃O(O₂CCH₃)₆(H₂O)₃][SiMo₁₂O₄₀]·11H₂O，鎢類似物可通過相似方法反應得到。^[3]

參考文獻

^ David M. Low, Gopalan Rajaraman, Madeleine Helliwell, Grigore Timco, Joris van Slageren, Roberta Sessoli, Stefan T. Ochsenbein, Roland Bircher, Christopher Dobe, Oliver Waldmann, Hans-Ulrich Güdel, Mark A. Adams, Eliseo Ruiz, Santiago Alvarez, Eric J. L. McInnes. A Family of Ferro- and Antiferromagnetically Coupled Decametallic Chromium(III) Wheels. Chemistry - A European Journal. 2006-02-01, 12 (5): 1385–1396 [2023-03-21]. ISSN 0947-6539. doi:10.1002/chem.200501041 （英語）.
^ Batsanov, A. S.; Struchkov, Yu. T.; Gerbeleu, N. V.; Timko, G. A.; Manole, O. S. Synthesis and crystal structure of (μ3-oxo)hexa(benzoato)triaquatrichromium(III) perchlorate. Koordinatsionnaya Khimiya, 1994. 20 (11): 833-837.
^ Xiaoshu Qu, Lin Xu, Yunfeng Qiu, Guanggang Gao, Fengyan Li, Yanyan Yang. New Series of Porous Ionic Crystals Constructed from Various Polyoxometalate Anions and Macrocations: Syntheses, Crystal Structures, and Comparison with Diverse Spatial Arrangement. Zeitschrift für anorganische und allgemeine Chemie. 2007-06, 633 (7): 1040–1047 [2023-03-21]. doi:10.1002/zaac.200600330. （原始內容存檔於2023-03-21）（德語）.

[1] David M. Low, Gopalan Rajaraman, Madeleine Helliwell, Grigore Timco, Joris van Slageren, Roberta Sessoli, Stefan T. Ochsenbein, Roland Bircher, Christopher Dobe, Oliver Waldmann, Hans-Ulrich Güdel, Mark A. Adams, Eliseo Ruiz, Santiago Alvarez, Eric J. L. McInnes. A Family of Ferro- and Antiferromagnetically Coupled Decametallic Chromium(III) Wheels. Chemistry - A European Journal. 2006-02-01, 12 (5): 1385–1396 [2023-03-21]. ISSN 0947-6539. doi:10.1002/chem.200501041 （英語）.

[2] Batsanov, A. S.; Struchkov, Yu. T.; Gerbeleu, N. V.; Timko, G. A.; Manole, O. S. Synthesis and crystal structure of (μ3-oxo)hexa(benzoato)triaquatrichromium(III) perchlorate. Koordinatsionnaya Khimiya, 1994. 20 (11): 833-837.

[3] Xiaoshu Qu, Lin Xu, Yunfeng Qiu, Guanggang Gao, Fengyan Li, Yanyan Yang. New Series of Porous Ionic Crystals Constructed from Various Polyoxometalate Anions and Macrocations: Syntheses, Crystal Structures, and Comparison with Diverse Spatial Arrangement. Zeitschrift für anorganische und allgemeine Chemie. 2007-06, 633 (7): 1040–1047 [2023-03-21]. doi:10.1002/zaac.200600330. （原始內容存檔於2023-03-21）（德語）.

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