高氯酸錫
外觀
高氯酸錫 | |
---|---|
識別 | |
CAS號 | 33673-21-1 ![]() |
性質 | |
化學式 | Cl4O16Sn |
摩爾質量 | 516.51 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
高氯酸錫是一種無機化合物,化學式為Sn(ClO4)4。它可由六氧化二氯和四氯化錫反應,得到(ClO2)2Sn(ClO4)6後在真空中熱分解得到。[1]紅外和拉曼光譜表明該化合物中每個Sn周圍存在兩個單齒高氯酸根配體和四個橋聯雙齒高氯酸根配體。[1]它和四氯化錫反應,可以得到SnCl2(ClO4)2。[2]
參考文獻
[編輯]- ^ 1.0 1.1 Fourati, M.; Chaabouni, M. Synthesis and spectroscopic analysis of a new perchlorato complex: tin(IV) perchlorate(法文). Journal de la Societe Chimique de Tunisie (1988), 2(8), 35-39. ISSN 0253-1208
- ^ Fourati, Mohieddine; Chaabouni, Moncef; Belin, Claude; Pascal, Jean Louis; Potier, Jacqueline. Chemical behavior of perchlorato ligand with tin(IV). Syntheses and structural analyses of dichlorobis(perchlorato)tin(IV) [SnCl2(ClO4)2], dichlorobis(μ-perchlorato)tin(IV) [(SnCl2(ClO4)2)x], di(perchlorato)bis(μ-perchlorato)tin(IV), [(Sn(ClO4)4)x], and chloryl hexakis(perchlorato)stannate(IV), [(ClO2)2Sn(ClO4)6]. A first x-ray structural approach of a chloryl perchlorato metallate. New Journal of Chemistry (1990), 14(8-9), 695-700. ISSN 1144-0546.