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二(4-乙酰基苯基)甲烷

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二(4-乙酰基苯基)甲烷
别名 双(4-乙酰基苯基)甲烷
识别
CAS号 790-82-9  checkY
性质
化学式 C17H16O2
摩尔质量 252.31 g·mol−1
外观 白色[1]或浅黄色固体[2]
熔点 93—94 °C(366—367 K)[3]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二(4-乙酰基苯基)甲烷是一种类有机物,化学式为C17H16O2。它可由二苯基甲烷乙酰氯三氯化铝催化下于二氯甲烷(或二硫化碳[2])反应制得[3]。它在硝酸-硫酸混酸中于3 °C反应,可以得到二(2-硝基-4-乙酰基苯基)甲烷[4]。它可以被次溴酸钠氧化为二(4-羧基苯基)甲烷[1]

参考文献

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  1. ^ 1.0 1.1 Jeong, Woomin; Khazi, Mohammed Iqbal; Lee, Dong Geol; Kim, Jong-Man. Intrinsically Porous Dual-Responsive Polydiacetylenes Based on Tetrahedral Diacetylenes. Macromolecules. 2018-12-26, 51 (24): 10312–10322. doi:10.1021/acs.macromol.8b02294. 
  2. ^ 2.0 2.1 Truccolo, Giada; Tessari, Zeno; Tessarolo, Jacopo; Quici, Silvio; Armelao, Lidia; Rancan, Marzio. A Cu( ii ) metallocycle for the reversible self-assembly of coordination-driven polyrotaxane-like architectures. Dalton Transactions. 2018, 47 (35): 12079–12084. doi:10.1039/C8DT02693A. 
  3. ^ 3.0 3.1 Zaitsev, B. A.; Shvabskaya, I. D. Divinyl aromatic compounds and Di(methacrylates) prepared by acid-catalyzed transformations of bis[4-(1-hydroxyethyl)phenyl]alkanes. Russian Journal of Applied Chemistry. 2011-10, 84 (10): 1783–1794. doi:10.1134/S1070427211100181. 
  4. ^ Tashiro, Masashi; Yamato, Takehiko; Fukata, Gouki; Fukuda, Yasuhisa. Friedel-Crafts chemistry. 6. Substituent effects on the ipso nitration and the novel nitration of some diphenylmethanes. The Journal of Organic Chemistry. 1981-05, 46 (11): 2376–2379. doi:10.1021/jo00324a032.