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4-羧基苯硼酸

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4-羧基苯硼酸
英文名 4-boronobenzoic acid
识别
CAS号 14047-29-1  checkY
性质
化学式 C7H7BO4
摩尔质量 165.94 g·mol−1
熔点 219—220 °C(492—493 K)[1]
沸点 236—237 °C(509—510 K)(分解)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

4-羧基苯硼酸是一种有机硼酸,化学式为C7H7BO4

合成

[编辑]

4-溴苯硼酸和硼酸三异丙酯反应,先后用正丁基锂盐酸处理,可以得到4-羧基苯硼酸。[3]4-甲基苯硼酸[4]4-甲酰基苯硼酸[5]的氧化反应也可用于制备4-羧基苯硼酸。

参考文献

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  1. ^ H. R. Snyder, Albert J. Reedy, Wm. J. Lennarz. Synthesis of Aromatic Boronic Acids. Aldehydo Boronic Acids and a Boronic Acid Analog of Tyrosine 1. Journal of the American Chemical Society. 1958-2, 80 (4): 835–838 [2019-04-19]. ISSN 0002-7863. doi:10.1021/ja01537a021. (原始内容存档于2019-09-18) (英语). 
  2. ^ Paweł Kurach, Sergiusz Luliński, Janusz Serwatowski. One-Pot Generation of Lithium (Lithiophenyl)trialkoxyborates from Substituted Dihalobenzenes (Hal = Br, I) and Their Derivatization with Electrophiles. European Journal of Organic Chemistry. 2008-6, 2008 (18): 3171–3178 [2019-04-19]. doi:10.1002/ejoc.200800245 (英语). 
  3. ^ Wenjie Li, Dorian P. Nelson, Mark S. Jensen, R. Scott Hoerrner, Dongwei Cai, Robert D. Larsen, Paul J. Reider. An Improved Protocol for the Preparation of 3-Pyridyl- and Some Arylboronic Acids. The Journal of Organic Chemistry. 2002-7, 67 (15): 5394–5397 [2019-04-19]. ISSN 0022-3263. doi:10.1021/jo025792p. (原始内容存档于2019-09-18) (英语). 
  4. ^ Jan C. Namyslo, Dieter E. Kaufmann. Chemical improvement of surfaces. Part 1: Novel functional modification of wood with covalently bound organoboron compounds. Holzforschung. 2009-01-01, 63 (5) [2019-04-19]. ISSN 1437-434X. doi:10.1515/HF.2009.112. (原始内容存档于2018-06-07). 
  5. ^ Safacan Kolemen, Tugba Ozdemir, Dayoung Lee, Gyoung Mi Kim, Tugce Karatas, Juyoung Yoon, Engin U. Akkaya. Remote-Controlled Release of Singlet Oxygen by the Plasmonic Heating of Endoperoxide-Modified Gold Nanorods: Towards a Paradigm Change in Photodynamic Therapy. Angewandte Chemie International Edition. 2016-03-07, 55 (11): 3606–3610 [2019-04-19]. doi:10.1002/anie.201510064 (英语).