双(三苯基膦)叠氮化亚铵

双(三苯基膦)叠氮化亚铵
识别
CAS号	38011-36-8
SMILES	[N-]=[N+]=[N-].N(=P(C=1C=CC=CC1)(C=2C=CC=CC2)C=3C=CC=CC3)[P+](C=4C=CC=CC4)(C=5C=CC=CC5)C=6C=CC=CC6;
性质
化学式	C36H30N4P2
摩尔质量	580.6 g·mol−1
外观	无色晶体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

双(三苯基膦)叠氮化亚铵是一种有机磷化合物，化学式为(C₃₆H₃₀NP₂)N₃。它可由氨基三苯基叠氮化𬭸在200~210 °C热分解得到，^[1]或由双(三苯基膦)氯化亚铵和碱金属叠氮化物的复分解反应制得。^[2]它和氢溴酸或高氯酸反应，可以得到相应的溴化物或高氯酸盐。^[1]它可用于制备一些叠氮配合物。^[3]

参考文献

^ ^1.0 ^1.1 Cookson, R. C.; Hughes, A. N. Pyrolysis of triphenylphosphiniminium azide. Journal of the Chemical Society, 1963. pp 6061-6062. doi:10.1039/JR9630006039
^ Martinsen, Arve; Songstad, Jon. Preparation and properties of some bis(triphenylphosphine)iminium salts, [(Ph₃P)₂N]X. Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 1977. 31 (8): 645-650. ISSN 0302-4377.
^ Haiges, Ralf; Rahm, Martin; Christe, Karl O. Unprecedented Conformational Variability in Main Group Inorganic Chemistry: the Tetraazidoarsenite and -Antimonite Salts A⁺[M(N₃)₄]⁻ (A = NMe₄, PPh₄, (Ph₃P)₂N; M = As, Sb), Five Similar Salts, Five Different Anion Structures. Inorganic Chemistry (American Chemical Society (ACS)). 2012-12-07, 52 (1): 402–414. ISSN 0020-1669. doi:10.1021/ic3021996.

[Notes1157-1] 1.0 ^1.1 Cookson, R. C.; Hughes, A. N. Pyrolysis of triphenylphosphiniminium azide. Journal of the Chemical Society, 1963. pp 6061-6062. doi:10.1039/JR9630006039

[2] Martinsen, Arve; Songstad, Jon. Preparation and properties of some bis(triphenylphosphine)iminium salts, [(Ph₃P)₂N]X. Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry, 1977. 31 (8): 645-650. ISSN 0302-4377.

[3] Haiges, Ralf; Rahm, Martin; Christe, Karl O. Unprecedented Conformational Variability in Main Group Inorganic Chemistry: the Tetraazidoarsenite and -Antimonite Salts A⁺[M(N₃)₄]⁻ (A = NMe₄, PPh₄, (Ph₃P)₂N; M = As, Sb), Five Similar Salts, Five Different Anion Structures. Inorganic Chemistry (American Chemical Society (ACS)). 2012-12-07, 52 (1): 402–414. ISSN 0020-1669. doi:10.1021/ic3021996.

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