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钨酸亚铊

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钨酸亚铊
识别
CAS号 13566-10-4  checkY
性质
化学式 O4Tl2W
摩尔质量 656.6 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

钨酸亚铊是一种无机化合物,化学式为Tl2WO4。它可由三氧化二铊碳酸亚铊三氧化钨加热反应制得,[1][2]或由硝酸亚铊钨酸钠在水溶液中反应得到。[3]它可以以三方晶系P3m1空间群结晶,晶胞参数a=6.278(1) Å,b=8.099(2) Å,Z=2。[4]它和三氧化钨加热反应,可以得到Tl2W2O7和Tl2W4O13[5]

参考文献

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  1. ^ Macarovici, Dan; Gaultier, Max; Courtine, Pierre. Thermal synthesis and crystalline structure of thallium tungstate. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques (1968), 266(26), 1777-1779. ISSN 0567-6541.
  2. ^ R.P. Rastogi; B.L. Dubey; Lakshmi; Ishwar Das (1977). Solid-state chemistry of thallous tungstates. J. Inorg. Nucl. Chem., 39 (12). doi:10.1016/0022-1902(77)80390-4.
  3. ^ Goudarzi, Mojgan; Mir, Noshin; Amiri, Omid; Salavati-Niasari, Masoud. Photocatalytic degradation of antibiotic using Ni-doped thallium(I) orthotungstate nanorods: Hydrothermal synthesis and characterization. Journal of Alloys and Compounds (2021), 874, 159856. doi:10.1016/j.jallcom.2021.159856.
  4. ^ Okada, K.; Ossaka, J.; Iwai, S. Structure of dithallium tungstate(VI). Acta Crystallographica, Section B: Structural Crystallography and Crystal Chemistry (1979), B35(9), 2189-2191. doi:10.1107/S0567740879008736.
  5. ^ Arkhincheeva, S. I.; Bazarova, Zh. G.; Mokhosoev, M. V.; Munkueva, S. D. Reaction of thallium(I) tungstate with tungsten trioxide(俄文). Zhurnal Neorganicheskoi Khimii (1988), 33(8), 2089-2091. ISSN 0044-457X.